Research Highlights

Detlef-M. Smilgies

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2023

Inkjet-printed Perovskite Pixels

inkjetting perovskites  We present a facile method of writing single perovskite pixels onto flexible substrates by inkjet printing of precursor solution. The optimum amount of material per pixel was determined using multipass printing. The surface morphology and surface energy of the substrate were optimized to obtain welldefined pixels with a resolution of 500 dots per inch or higher.

Directional crystallization via blade coating

directional crystallization  The coating of organic molecules from the solution phase can result in directional crystal growth under certain conditions, even on a smooth isotropic surface and without the need of any kind of graphoexpitaxial preparation of the substrate. Based on reviewing the results from a variety of coating techniques and coating parameters, we identified that it is crucial for the coating speed to match the growth speed of the fastest growing crystal plane to achieve a high degree of directional crystallization.

2022

Combining scattering and imaging:  microGIWAXS tomography

 GIWAXS CT  Scattering provides detailed insight into the structure of materials, however lacks the immediate intuitive understanding that imaging techniques provide. A collaboration of Binghamton University, Lawrence University, Brookhaven National Lab and Stanford University has attempted to remediate this situation. Combining state-of-the-art microbeam GIWAXS with tomographic methods the team imaged the structure of an organinc semiconductor in a transistor array ...            

Detlef-M. Smilgies, Margaret K. A. Koker, Ruipeng Li, Leo Shaw, and Zhenan Bao: "Grazing-Incidence Texture Tomography and Diffuse Reflectivity Tomography of an Organic Semiconductor Device Array", Chemistry—Methods 2022, e202200016.

Spotlight on real-time in-situ processing of lead halide perovskites

Perovskite Highlight   Real-time in-situ GIWAXS has revealed much detail on the intricate processing stages of lead halide perovskites, one of the most promising class of materials for thin film solar cells. An overview is given on techniques (one-step and two-step spin coating, blade coating) as well as on basic materials, mixed anion cation systems and solvents...

Dounya Barrit, Ming-Chun Tang, Rahim Munir, Ruipeng Li, Kui Zhao, and Detlef-M. Smilgies: "Processing of Lead Halide Perovskite Thin Films Studied with In-Situ Real-Time X-ray Scattering", ACS Appl. Mater. Interfaces 2022, 14, 23, 26315–26326.

2021

Perspective on block copolymer structure characterization using GISAXS

GISAXS   GISAXS has proven to be a powerful method to characterize the structure of block copolymer  (BCP) thin films and BCP-based nanocomposite structures. Even more so, the structure formation pathway and self-assembly kinetics can be studied in great detail in real time using in-situ sample cells. This overview introduces the reader to GISAXS scattering theory, good experimental practice, design and application of in-situ apparatus, as well as selected experimental examples. The perspective concludes with an overview of emergent techniques and applications.

Detlef-M. Smilgies: "GISAXS: A versatile tool to assess structure and self-assembly kinetics in block copolymer thin films", J. Polym. Sci. 2022, 60, 1023-1041.

2020

Plasmonic multilayers based on DNA-coated gold nanoparticles

DNA-AuNP-multilayers   Gold nanoparticles coated with single-stranded DNA ligands have a powerful dual functionality: The DNA ligands can be engineered with highly specific end groups that selectively attach to DNA strands on the surfaces of viruses and bacteria, or to detect microRNAs in the bloodstream that are early cancer indicators. The gold core serves as a light amplifier via the surface plasmon resonance for detection of agents using for instance surface-enhanced Raman spectroscopy.


2019

That's it: Detlef retires as a beamline scientist after 23 years of user support at ESRF and CHESS

Detlef   At this point I would like to thank all my faithful users and collaborators for bringing novel materials and exciting ideas to the beamlines I was in charge of. It has been a wild ride all over the nanoworld! Rock on!


Bioinspired membranes: Teaching an old dog new tricks

bioinspired membranes   Living cells control input and output from the cell to the surrounding medium with highly specific channels formed by membrane proteins. In order to make this specificity available to membranes...


We've got the beets: Food consumers may see red, naturally

beet extract   Cornell food scientists hunting for a stable, natural red food coloring to replace artificial dyes have unlocked a secret ...

2018

D-line going out with a bang!

D-line farewell   During just the final half year of D-line operation in 2018, D-line users have published 19 articles in renowned journals on ex-situ and in-situ studies of soft materials...

Luisa Whittaker-Brooks Named Talented Twelve

Luisa Whitaker-Brooks   Congratulations, Luisa Whittaker-Brooks, University of Utah and CHESS User, who has been named one of the 2018 Talented 12 by Chemical & Engineering News.

Controlling morphologies at the nano-scale

GISAXS map  Nano-structure of thin polymer films is precisely controlled by new type of annealing

Origin of Vertical Orientation in Two-Dimensional Metal Halide Perovskites and its Effect on Photovoltaic Performance

vertically oriented organic 2D perovskites  Metal Halide Perovskites (MHPs) are poised to revolutionize the field of optoelectronic materials with their phenomenal performance in solar cells, light emitting diodes (LEDs), photodetectors and lasers.

Congratulations TeraPore Technologies!

TeraPore Technol   TeraPore Technologies, the developer of advanced nanofiltration membrane systems for bioprocess and other applications, announced that it has completed a $6M Series A financing round.


2017

Watching nanocrystals in action

periodic table of nanocrystals   The assembly of colloidal nanocrystal building blocks into ordered superlattices presents many scientifically interesting and technologically important research challenges to create programmable matter from “crystals-of-crystals”...

2D organic-inorganic perovskites pave the way to novel low-cost solar cells

2D organic perovskite   Organic-inorganic lead iodide perovskites are a much studied materials class that have reached solar cell efficiencies above 22% – on par with amorphous silicon – in only a few years after discovery...

The Real Thing: D-line sample robot serves first user group

D-line robot   Combinatorial thin film research can comprise hundreds of samples grown with slightly different compositions or processing conditions ...

CHESS hosts first MaMaSELF student

MaMaSELF   The MaMaSELF program, short for Masters in Material Science Exploring Large-scale Facilities, is a two-year European Masters program in materials science ...

CHESS facility helps scale up solar cells

detlef   Scientists and engineers are constantly working to improve the performance or solar cells ...

Formation of high-performance photovoltaic materials from solution

perovskite   Mixed organic-inorganic halide perovskite materials have been in the spotlight in the photovoltaics research community ...


2016

In-situ x-ray scattering studies of solvent vapor annealing reviewed

polymer ore-organization   Based on research spanning more than 15 years at CHESS and at HASYLAB, Christine M. Papadakis at the Technical University of Munich (TUM), Germany, Dorthe Posselt at Roskilde University, Denmark, and CHESS staff scientist Detlef Smilgies published a comprehensive review on in-situ solvent vapor annealing processes ...

Run, run, as fast as you can - laser spike annealing of block copolymer films

scanning bcp   Thermal annealing is a standard method for bringing block copolymer films into their thermal equilibrium morphology. However, typical thermal annealing is slow ...

laser annealing   The ability to precisely control every aspect of a material, even at the nanoscale, is of critical importance in a host of applications ...

Secrets of membrane formation revealed

membranes   The SNIPS process (Self-assembly plus Non-solvent-Induced Phase Separation) is a newly developed method to create asymmetric membranes with well-defined pore sizes in the top separation layer, for instance for ultrafiltration of proteins or viruses...

Workshop 4 recap: Materials Design and Processing from Nano to Mesoscale

Nano Workshop   This workshop sought to bring together scientists seeking to build and understand new materials achieving exceptional properties through assemblies of either organic or inorganic building blocks...


Knife-coated organic semiconductor blends with mobilities on par with single crystals

organic transistor  The paramount goal of organic electronics is to achieve high mobility in organic transistors within solution-based coating methods ...


Transient phases during coating of an organic semiconductor film

pen writing set-up  A key element for bringing organic electronics to the market place is the understanding of the microstructure formation during coating and printing. The deposit microstructure limits the device performance...


Former CHESS user Shawn Tan wins Innovators award in new field of nanoplasmonics

plasmonic nanoMonet  This past November ten young innovators made it to EmTech Singapore's Innovators Under 35 list, selected from over 100 applicants from Asia and Australasia...


2015


NASA Early Career Faculty Award for CHESS user Joshua Choi

Josh Choi U Virginia  CHESS user Joshua Choi, an assistant professor at the University of Virginia, won a prestigious NASA Early Career Faculty Award ...


Impact of solvent and polymer additives on heterojunction solar cells

role of additives  When building solar cells based on organic bulk heterojunctions (BHJ), donor and acceptor semiconducting materials are deposited from solution ...


Key to cooperative Oswald ripening unraveled

role of halides  Through diligent chemistry work on purifying small gold nanoparticles and then reintroducing a variety of additives ...


CHESS Student Paper Prize to Gaurav "Gino" Giri

UM15 paper prize  CHESS Director Joel Brock was pleased to announce this year’s winner of the CHESS Student Paper Prize as Gaurav “Gino” Giri ...


Poster Prize winners honored at CHESS Users' Meeting

UM15 poster prizes  An important part of the annual CHESS Users’ Meeting is the display and discussion surrounding users who present their work via posters ...


Switchable Nanorods

switchable nanorods  Nanorods are elongated nanoparticles with aspect ratios of typically 3:1 to 10:1 and thus have interesting structural and optical anisotropies ...

From fibers to fashion

fibers to fashion   D1 user Lina Botero of Cornell Fiber Science & Apparel Design in the news: Lighted clothing that flashes to beat of music will hit runway ...

Anomalous thermal behavior of small gold nanoparticles

reverse melting  When we heat up something, we usually expect it to come out less ordered, e.g. ice turns to water ...

The first three D-line chemical engineering masters take up jobs in industry

ChemE MEng students  With the availability of the Sample Environment Lab, CHESS staff scientist Detlef Smilgies, also an adjunct associate professor at the Cornell School of Chemical and Biomolecular Engineering, took three aspiring chemical engineers under his wings...


2014

Graduate students at CHESS mentor undergraduate engineers

Patrick and Zeenia  This fall semester, Cornell High Energy Synchrotron Source (CHESS) furthered its educational goals...

Billions of 'nanoreactors' inform materials design

billions of nanoreactors  Imagine building a chemical reactor small enough to study nanoparticles a billionth of a meter across...


Nanometer-scale chemical reactors based ...

nanoreactors  based on binary nancrystal superlattices...


The CHESS Sample Environment Lab

News Icon  In order to further the development of Real-Time In-situ Multiprobe (RIM) experiments...


X-rays, computer simulations reveal organic crystal growth

News Icon  Global research team unveils new mechanism of controlled crystallization ...


2013

Self-organized crystallinity paves the way to novel all-polymer solar cell

P3HT crystal structure  Bulk hetero junctions (BHJ) constitute a promising route for low-cost solar cell...


Add a little something ...

News Icon  Additives control the structural evolution in small-molecule organic solar cells ...


Detlef Smilgies appointed Adjunct Associate Professor at Cornell Chemical Engineering

News Icon  CHESS staff scientist Detlef Smilgies was recently appointed ...

Nanoparticles show unusual fusion

News Icon  Random process leads to surprising organization …


Gaurav Giri Receives the Klein Development Award

News Icon  For solution shearing of organic semiconducting molecules...


Organic Transistors

News Icon  A little vapor goes a long way…

Spreading the Butter on the Toast Just So

News Icon   High-Performance organic transistors by novel deposition technique…

Shake It Up

News Icon   Insights on printing thin films for organic electronics devices...

CHESS Graduate Student User Kaifu Bian

News Icon   receives Austin Hooey Award 2012 for Outstanding Thesis Research...



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